Research and Application of Materials Science

Research Progress of Non-oxide and High Entropy Ceramic Coatings

CHENJunshuai (Hebei Provincial Engineering Research Center of Metamaterial and Micro-device, School of Materials Science and Engineering, Shijiazhuang Tiedao University), WANGYulong (Hebei Provincial Engineering Research Center of Metamaterial and Micro-device, School of Materials Science and Engineering, Shijiazhuang Tiedao University), WANGZeyu (Hebei Provincial Engineering Research Center of Metamaterial and Micro-device, School of Materials Science and Engineering, Shijiazhuang Tiedao University), SHENXue (Hebei Provincial Engineering Research Center of Metamaterial and Micro-device, School of Materials Science and Engineering, Shijiazhuang Tiedao University), DUTengyu (Hebei Provincial Engineering Research Center of Metamaterial and Micro-device, School of Materials Science and Engineering, Shijiazhuang Tiedao University), GONGYubo (CARS Engineering Consulting Corporation Limited), YANGZhigang (Hebei Provincial Engineering Research Center of Metamaterial and Micro-device, School of Materials Science and Engineering, Shijiazhuang Tiedao University), YUGang (Hebei Provincial Engineering Research Center of Metamaterial and Micro-device, School of Materials Science and Engineering, Shijiazhuang Tiedao University)


Ceramic coatings play a key role in extending the service life of materials in aerospace and energy fields by protecting materials from high temperature, oxidation, corrosion and thermal stress. Non-oxide and high entropy ceramics are new emerging coating materials which have been researched and developed in recent years. Compared with traditional oxide ceramics, non-oxide ceramics have better high temperature stability, oxidation resistance and erosion resistance. These characteristics make non-oxide ceramics perform well in extreme environments. It is particularly noteworthy that the non-oxide high entropy ceramic is a uniform solid solution composed of at least four or five atoms. Their unique structure and outstanding properties show great potential application in the field of coating. In this paper, the researches about regulating microstructure, preparation technology and properties of nitride and its high entropy system, carbide and its high entropy system and boride and its high entropy system in coating field are summarized, and their future development and prospects are prospected.


Nitride; Carbide; Boride; High entropy ceramic coating

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BAZHIN P M, TITOV N V, ZHIDOVICH A O, et al. Features of the carbo-vibroarc surfacing in the development of multicomponent cermet wear-resistant coatings[J]. Surface and Coatings Technology, 2022(429):12795.

BODNYA I S, TIMOSHENKO V P. Numerical modeling of a wing leading-edge thermal regimes for a reusable space vehicle[J]. RUDN Journal of Engineering Researches, 2018,19(1):7-21.

RICHARDSON P J, KEAST V J, CUSKELLY D T, et al. Theoretical and experimental investigation of the W-Al-B and Mo-Al-B systems to approach bulk WAlB synthesis[J]. Journal of the European Ceramic Society, 2021,41(3):1859-1868.

CHENG Y, HU P, DONG S, et al. Dual bionics of structure and preparation: Gradient architectured carbon/ceramic composite as light as water but bearing ultra-high temperature max to 2500 C[J]. Composites Part B: Engineering, 2023(265):110963.

LI C, FAN H, NI L, et al. Phase transformation and thermal conductivity of the APS Y2O3 doped HfO2 coating with hybrid structure[J]. Ceramics International, 2022,48(14):19633-19643.

CUI Y J, LI J E, WANG B L, et al. Thermally induced delamination and buckling of a ceramic coating with temperature-dependent material properties from porous substrate at high temperatures[J]. Acta Mechanica, 2020,231(6):2143-2154.

Yang Y Z, Yang J l , Fang D N . Research progress on thermal protection materials and structures of hypersonic vehicles[J]. Applied Mathematics and Mechanics, 2008,29(1):51–60.

Gorr B, Schellert S, Muller F, et al. Current Status of Research on the Oxidetion Behavior of Refractory High Entropy Alloys[J]. Advanced Engineering materials, 2021,23(5):2001047.

Yang S Q, Yang H Z, Shi Q, et al. Investigation on failure mechanism and interfacial diffusion behavior of NiCoCrAlYTa coating at high temperature[J]. Coeeosion Science, 2024,229:111871.

WANG D, LIN S-S, DUAN D-Y, et al. Thermal shock resistance of Cr/CrN/Cr/CrAlN multilayer anti-erosion coating[J]. Surface and Coatings Technology, 2023(470):129776.

ZAKUTAYEV A, PERKINS C L. Influence of Protection Layers on Thermal Stability of Nitride Thin Films[J]. physica status solidi (RRL)-Rapid Research Letters, 2021,15(8):2100178.

REN J, XU L, LUO J, et al. Hydrothermal oxidation of titanium nitride coating for enhanced corrosion resistance in fluoride-containing acidic solution[J]. Materials Letters, 2023(335): 133790.

BAKKAR S, ZUCHA E, BEAM J, et al. A new approach to protect and extend longevity of the thermal barrier coating by an impermeable layer of silicon nitride[J]. Journal of the American Ceramic Society, 2023,106(10):6221-6229.

SAJI V S. 2D hexagonal boron nitride (h-BN) nanosheets in protective coatings: A literature review[J]. Heliyon, 2023,9(9):19362.

DE LIMA T A D M, DE LIMA G G, DA COSTA L N, et al. Evaluation of titanium nitride coatings in bandsaw blades for wood splitting by cold plasma[J]. Wood Material Science & Engineering, 2021,18(1):130-140.

GANESHKUMAR S, SINGH B K, KUMAR S D, et al. Study of Wear, Stress and Vibration Characteristics of Silicon Carbide Tool Inserts and Nano Multi-Layered Titanium Nitride-Coated Cutting Tool Inserts in Turning of SS304 Steels[J]. Materials (Basel), 2022,15(22):7994-8006.

TAKESUE S, MORITA T, MISAKA Y, et al. Rapid formation of titanium nitride coating by atmospheric-controlled induction-heating fine particle peening and investigation of its wear and corrosion resistance[J]. Results in Surfaces and Interfaces, 2023(11):100121.

LIAO S, YANG L, SONG Z, et al. Effect of nitrogen content on the mechanical and biological properties of tantalum nitride coatings[J]. Surface and Coatings Technology, 2023(464): 129544.

KIM I I, SUROVTSEVA M A, POVESHCHENKO O V, et al. Biocompatibility of Titanium Oxynitride Coatings Deposited by Reactive Magnetron Sputtering[J]. Bulletin of Experimental Biology and Medicine, 2022,173(6):779-782.

QIAN H, CHEN S, WANG T, et al. Silicon nitride modified enamel coatings enable high thermal shock and corrosion resistances for steel protection[J]. Surface and Coatings Technology, 2021(421):127474.

YAN P, CHEN K, WANG Y, et al. Design and Performance of Property Gradient Ternary Nitride Coating Based on Process Control[J]. Materials, 2018,11(5):758-770.

YANG S, GUO T, YAN X, et al. High-density twin boundaries in transition metal nitride coating with boron doping[J]. Acta Materialia, 2023(255):119033.

MAKGAE O A, LENRICK F, BUSHLYA V, et al. Visualising microstructural dynamics of titanium aluminium nitride coatings under variable-temperature oxidation[J]. Applied Surface Science, 2023(618):156625.

ZHANG Z, YANG Z, HE G. Alleviating the adverse influence of nitride coating on the fatigue performance of Ti6Al4V by Ni alloying[J]. Journal of Materials Research and Technology, 2023(26):517-529.

ZHANG Y L, CHEN F, ZHANG Y, et al. Corrosion and tribocorrosion behaviors of ternary TiZrN coating on 304 stainless steel prepared by HiPIMS[J]. Materials Today Communications, 2022(31):103258.

MA A, LIU D, ZHANG X, et al. Solid particle erosion behavior and failure mechanism of TiZrN coatings for Ti-6Al-4V alloy[J]. Surface and Coatings Technology, 2021(426):127701.

MAKSAKOVA O V, ZHANYSSOV S, PLOTNIKOV S V, et al. Microstructure and tribomechanical properties of multilayer TiZrN/TiSiN composite coatings with nanoscale architecture by cathodic-arc evaporation[J]. Journal of Materials Science, 2020,56(8):5067-5081.

CHEMAA K, HASSANI S, KEZRANE M, et al. Tribological Investigation of W-Ti-N Thin Film on Plasma Nitrided Stainless-Steel Multilayer Coating[J]. Jom, 2023,75(8):3111-3120.

STASIAK T, SOUČEK P, BURŠíKOVá V, et al. Synthesis and characterization of the ceramic refractory metal high entropy nitride thin films from Cr-Hf-Mo-Ta-W system[J]. Surface and Coatings Technology, 2022(449):128987.

HSU S Y, LAI Y T, CHANG S Y, et al. Combinatorial synthesis of reactively co-sputtered high entropy nitride (HfNbTiVZr)N coatings: Microstructure and mechanical properties[J]. Surface and Coatings Technology, 2022(442):128564.

DIPPO O F, MESGARZADEH N, HARRINGTON T J, et al. Bulk high-entropy nitrides and carbonitrides[J]. Scientific Reports, 2020,10(1):21288.

LI F, CUI W, SHAO Y, et al. Preparing high-entropy ceramic films from high-entropy alloy substrate[J]. Materials Chemistry and Physics, 2022(287):126365.

KRETSCHMER A, BOHRN F, HUTTER H, et al. Analysis of (Al,Cr,Nb,Ta,Ti)-nitride and -oxynitride diffusion barriers in Cu-Si interconnects by 3D-Secondary Ion Mass Spectrometry[J]. Materials Characterization, 2023(197):112676.

NI D, CHENG Y, ZHANG J, et al. Advances in ultra-high temperature ceramics, composites, and coatings[J]. Journal of Advanced Ceramics, 2021,11(1):1-56.

WU S, XU X, YANG S, et al. Data-driven optimization of hardness and toughness of high-entropy nitride coatings[J]. Ceramics International, 2023,49(13):21561-21569.

SI Y, WANG G, WEN M, et al. Corrosion and friction resistance of TiVCrZrWNx high entropy ceramics coatings prepared by magnetron sputtering[J]. Ceramics International, 2022,48(7):9342-9352.

REN B, ZHAO R F, ZHANG G P, et al. Microstructure and properties of the AlCrMoZrTi/(AlCrMoZrTi)N multilayer high-entropy nitride ceramics films deposited by reactive RF sputtering[J]. Ceramics International, 2022,48(12):16901-16911.

HAHN R, KIRNBAUER A, BARTOSIK M, et al. Toughness of Si alloyed high-entropy nitride coatings[J]. Materials Letters, 2019(251):238-240.

MOSKOVSKIKH D, VOROTILO S, BUINEVICH V, et al. Extremely hard and tough high entropy nitride ceramics[J]. Scientific Reports, 2020,10(1):19874.

CHANG C H, YANG C B, SUNG C C, et al. Structure and tribological behavior of (AlCrNbSiTiV)N film deposited using direct current magnetron sputtering and high power impulse magnetron sputtering[J]. Thin Solid Films, 2018(668):63-68.

CHEN T K, WONG M S, SHUN T T, et al. Nanostructured nitride films of multi-element high-entropy alloys by reactive DC sputtering[J]. Surface and Coatings Technology, 2005,200(5-6):1361-1365.

BRAIC V, VLADESCU A, BALACEANU M, et al. Nanostructured multi-element (TiZrNbHfTa)N and (TiZrNbHfTa)C hard coatings[J]. Surface and Coatings Technology, 2012(211):117-121.

FENG X, ZHANG K, ZHENG Y, et al. Chemical state, structure and mechanical properties of multi-element (CrTaNbMoV)Nx films by reactive magnetron sputtering[J]. Materials Chemistry and Physics, 2020(239):121991 .

XU W, LIAO M, LIU X, et al. Microstructures and properties of (TiCrZrVAl)N high entropy ceramics films by multi-arc ion plating[J]. Ceramics International, 2021,47(17):24752-24759.

WANG J, SHU R, CHAI J, et al. Xe-ion-irradiation-induced structural transitions and elemental diffusion in high-entropy alloy and nitride thin-film multilayers[J]. Materials & Design, 2022(219):110749.

LU X, ZHANG C, ZHANG X, et al. Dependence of mechanical and tribological performance on the microstructure of (CrAlTiNbV)Nx high-entropy nitride coatings in aviation lubricant[J]. Ceramics International, 2021,47(19):27342-27350.

ZHOU Q, XU F, GAO C, et al. Design of high-performance high-entropy nitride ceramics via machine learning-driven strategy[J]. Ceramics International, 2023,49(15):25964-25979.

MICALLEF C, ZHUK Y, ARIA A I. Recent Progress in Precision Machining and Surface Finishing of Tungsten Carbide Hard Composite Coatings[J]. Coatings, 2020,10(8):731.

ZHAO Z, HUI P, LIU F, et al. Fabrication of niobium carbide coating on niobium by interstitial carburization[J]. International Journal of Refractory Metals and Hard Materials, 2020(88):105187.

KHAN M, AHMAD S, ZAIDI S, et al. Titanium carbide coating on graphene nanoplatelets[J]. Journal of Materials Research and Technology, 2020,9(3):3075-3083.

LIU W, YANG J, QIU Y, et al. Titanium carbide’s effects on coatings formed on D16T aluminum alloy by plasma electrolytic oxidation[J]. Anti-Corrosion Methods and Materials, 2020,67(1):48-58.

CHEN Z, LI H, REN L, et al. Effect of Tungsten Carbide Addition on the Wear Resistance of Flame-Sprayed Self-Lubricating Ni-Graphite Coatings[J]. Journal of Materials Engineering and Performance, 2020,29(2):1156-1164.

MEN X, TAO F, GAN L, et al. Erosion behaviour of cobalt-based coatings with different carbide contents under high-speed propellant airflow[J]. Surface Engineering, 2020,36(11):1210-1218.

LI H, YANG X, CHEN Y, et al. Microstructure and properties of Cr-Nb carbide coatings on graphite via powder immersion reaction assisted coating[J]. Surface and Coatings Technology, 2023(455):129226.

PANA I, VLADESCU A, CONSTANTIN L R, et al. In Vitro Corrosion and Tribocorrosion Performance of Biocompatible Carbide Coatings[J]. Coatings, 2020,10(7):654.

GOVANDE A R, RATNA SUNIL B, DUMPALA R. Wear and corrosion behaviour of the cryogenically treated tungsten carbide coatings[J]. Surface Engineering, 2023,39(3):326-338.

KHATER M A, BOUAZIZ S A, GARRIDO M A, et al. Mechanical and tribological behaviour of titanium boride coatings processed by thermochemicals treatments[J]. Surface Engineering, 2020,37(1):101-110.

DIPPO O F, MESGARZADEH N, HARRINGTON T J, et al. Bulk high-entropy nitrides and carbonitrides[J]. Sci Rep, 2020,10(1):21288.

WANG Y, ZHANG B, ZHANG C, et al. Ablation behaviour of (Hf-Ta-Zr-Nb)C high entropy carbide ceramic at temperatures above 2100 °C[J]. Journal of Materials Science & Technology, 2022(113):40-47.

Zhao K, Ye F, Cheng L F, et al. Formation of Ultra-High Temperature Ceramic Hollow Microspheres as Promising Lightweight Thermal Insulation Materials via a Molten Salt-Assisted Template Method[J]. ACS Applied Material & Interfaces, 2021,13(32):37388-37397.

ZHU Y, CHAI J, WANG Z, et al. Microstructural damage evolution of (WTiVNbTa)C5 high-entropy carbide ceramics induced by self-ions irradiation[J]. Journal of the European Ceramic Society, 2022,42(6):2567-2576.

TUNES M A, FRITZE S, OSINGER B, et al. From high-entropy alloys to high-entropy ceramics: The radiation-resistant highly concentrated refractory carbide (CrNbTaTiW)C[J]. Acta Materialia, 2023(250):118856.

HAI Z, ZIHAO W, HAO C, et al. Microstructure, Mechanical and Tribological Properties of High-Entropy Carbide Ceramics (VNbTaMoW)C5–SiC[J]. Powder Metallurgy and Metal Ceramics, 2023,61(7-8):451-458.

CAI F, NI D, BAO W, et al. Ablation behavior and mechanisms of Cf/(Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C–SiC high-entropy ceramic matrix composites[J]. Composites Part B: Engineering, 2022(243):110177.

LUO S C, GUO W M, PLUCKNETT K, et al. Low-temperature densification of high-entropy (Ti,Zr,Nb,Ta,Mo)C-Co composites with high hardness and high toughness[J]. Journal of Advanced Ceramics, 2022,11(5): 805-813.

BEILIN YE, TONGQI WEN, MANH CUONG NGUYEN, et al. First-principles study, fabrication and characterization of (Zr0.25Nb0.25Ti0.25V0.25)C high-entropy ceramics[J]. Acta Materialia,2019(170):15-23.

LINDNER T, LöBEL M, HUNGER R, et al. Boriding of HVOF-sprayed Inconel 625 coatings[J]. Surface and Coatings Technology, 2020(404):126456.

MIRHOSSEINI S H, MOSALLAEE M, RAZAVI M, et al. Reaction behavior and wear properties of in-situ air plasma-sprayed Al2O3-TiB2 composite coatings[J]. Journal of the European Ceramic Society, 2023,43(14):6482-6492.

ZENG X, LIU Z, TONG X, et al. Preparation and infrared emissivity of metal borides(metal=V,Mo,Fe) and MnO2 co-doped NiCr2O4 coatings[J]. Ceramics International, 2022, 48(4):5581-5589.

SALYI Z, KAPTAY G, KONCZ-HORVATH D, et al. Boride Coatings on Steel Protecting it Against Corrosion by a Liquid Lead-Free Solder Alloy[J]. Metallurgical and Materials Transactions B, 2022,53(2):730-743.

ZHANG H, PAN Y, ZHANG Y, et al. Sensitivity Analysis for Process Parameters in Mo2FeB2 Ternary Boride Coating by Laser Cladding[J]. Coatings, 2022,12(10):1420.

BAO J, YU Y, LIU B, et al. In Situ Ternary Boride: Effects on Densification Process and Mechanical Properties of WC-Co Composite Coating[J]. Materials (Basel), 2020,13(8):1995.

ZHANG H, AKHTAR F. Refractory multicomponent boron-carbide high entropy oxidation-protective coating for carbon-carbon composites[J]. Surface and Coatings Technology, 2021(425):127697.

KAHL B A, BERNDT C C, ANG A S M. Boride-based ultra-high temperature ceramic coatings deposited via controlled atmosphere plasma spray[J]. Surface and Coatings Technology, 2021(416):127128.

ÇAKIR M V. A Comparative Study on Tribocorrosion Wear Behavior of Boride and Vanadium Carbide Coatings Produced by TRD on AISI D2 Steel[J]. Protection of Metals and Physical Chemistry of Surfaces, 2022,58(3):562-573.

LöBEL M, LINDNER T, HANISCH N, et al. High-temperature wear behaviour of borided Inconel 718 HVOF coatings[J]. IOP Conference Series:Materials Science and Engineering, 2021,1147(1):012032.

DOñU RUIZ M A, GARCíA BUSTOS E D, DE LA MORA RAMIREZ T, et al. Characterization of Boride Coatings on AISI 8620 Steels without and with Hydrogen Permeation[J]. Advances in Materials Science and Engineering, 2022(2022):1-13.

MAYRHOFER P H, KIRNBAUER A, ERTELTHALER P, et al. High-entropy ceramic thin films; A case study on transition metal diborides[J]. Scripta Materialia, 2018(149):93-97.

ZHANG P, CHENG C, LIU B, et al. Multicomponent (Hf0.25Zr0.25Ti0.25Cr0.25)B2 ceramic modified SiC–Si composite coatings: In-situ synthesis and high-temperature oxidation behavior[J]. Ceramics International, 2022,48(9):12608-12624.

GUO L, WANG Y, LIU B, et al. In-situ phase evolution of multi-component boride to high-entropy ceramic upon ultra-high temperature ablation[J]. Journal of the European Ceramic Society, 2023,43(4):1322-1333.



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