Research and Application of Materials Science

Surface and Interfacial Bonding with Epoxy Adhesive of Flame Retardent Acrylonitrile-Butadiene-Styrene Copolymers (ABS)

WANGLulin (Guangzhou Super-Dragon Engineering Plastics Co. Ltd), XIANYeming (Guangzhou Super-Dragon Engineering Plastics Co. Ltd), DENGJuean (Guangzhou Super-Dragon Engineering Plastics Co. Ltd), HAOJianxin (Guangzhou Super-Dragon Engineering Plastics Co. Ltd), HAOYuanzeng (Guangzhou Super-Dragon Engineering Plastics Co. Ltd), YUWentao (Guangzhou Super-Dragon Engineering Plastics Co. Ltd)

Abstract


Flame retardants were widely used to expanding applications of acrylonitrile-butadiene-styrene copolymers (ABS) to daily life, heat generation, and energy storage. However, effect of flame retardants on surface properties such as wettability, adhesion and epoxy resins affinity were few studied. In this work, surface, epoxy resin adhesive as well as curing condition of ABS/ FRABS were investigated systematically. Results showed that processing temperature changing the ABS-flame retardant mixing from liquid-solid to liquid-liquid and affect the interface shear bonding strength. Best processing of rebonded ABS samples were curing under 0.7 kg, in 60 °C for 2 hours. Adhesion of epoxy to ABS/ FRABS remained for 90 days under soaking in 40 wt% sulfuric acid, showing the obvious chemical stability.

Keywords


ABS; Flame retardant; Epoxy resin; Surface adhesion

References


Kahraman M V, Akdemir Z S, Kartal I, et al. Preparation of fluorine containing hybrid coatings: investigation of coating performance onto ABS and PMMA substrates [J]. Polym. Advan. Technol, 2011(22):981-986.

Abbott A C, Tandon G P, Bradford R L, et al. Process-structure-property effects on ABS bond strength in fused filament fabrication [J]. Additive Manufacturing, 2018(19):29-38.

Zhang H, Kang Z, Sang J, et al. Surface metallization of ABS plastics for nickel plating by molecules grafted method [J]. Surface and Coatings Technology, 2018(340):8-16.

Chen D, Zhang Y, Bessho T, et al. Ag films with enhanced adhesion fabricated by solution process for solar reflector applications [J]. Sol. Energ. Mat. Sol. C, 2016(151):154-161.

Han X, Wang G, He Y, et al. Surface modification of ABS with Cr6+ free etching process in the electroless plating [J]. J. Adhes. Sci. Technol, 2018(32):2481-2493.

Altarawneh M, Saeed A, Al-Harahsheh M, et al. Thermal decomposition of brominated flame retardants (BFRs): Products and mechanisms [J]. Prog. Energ. Combust, 2019(70):212-259.

Huang G, Huo S, Xu X, et al. Realizing simultaneous improvements in mechanical strength, flame retardancy and smoke suppression of ABS nanocomposites from multifunctional graphene [J]. Composites Part B: Engineering, 2019(177):107377.

Zhan L, Zhao X, Ahmad Z, et al. Leaching behavior of Sb and Br from E-waste flame retardant plastics [J]. Chemosphere, 2020(245),125684.

Xia Y, Liu S, Wang X, et al. The Analysis of Synergistic Effects of Zeolites applied in Intumescent Halogen-free Flame-retardant ABS Composites [J]. Polym-Plast. Technol, 2008(11):613-618.

Martins P A , Valera T S , Tenório J A S , Estudo de sistemas retardantes de Chama sem Bromo para ABS [J]. Polímeros, 2014,24:572-578.

Lu C, Chen T, Cai X, Halogen-free Intumescent Flame Retardant for ABS/PA6/SMA Alloys. Journal of macromolecular science [J]. Physics, 2009(48):651-662.

Yi L, JiangsongY, Xufu C, Application of a novel halogen-free intumescent flame retardant for acrylonitrile-butadiene-styrene [J]. J. Appl. Polym. Sci, 2012(124):1475-1482.




DOI: https://doi.org/10.33142/rams.v6i2.14586

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Copyright (c) 2024 Lulin WANG, Yeming XIAN, Juean DENG, Jianxin HAO, Yuanzeng HAO, Wentao YU

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